ویرایش
90.9.30

اعتبار قیمت
90.11.30

لطفا پس از پایان اعتبار قیمت با شماره تلفن 88920648 تماس حاصل فرمائید

جهت دریافت کاتالوگ لطفا روی عکس  کلیک کنید

Chemical Properties

Literature References

For an example of the Adams modification of the Gattermann reaction for formylation of aromatics, see: Org. Synth. Coll., 3, 549 (1955). For in situ cyanosilylation of aldehydes and ketones with Zn(CN)₂ and TMS chloride, as an alternative to Trimethyl­silyl­ cyanide, A19598, see: Org. Synth. Coll., 7, 521 (1990).

Used in combination with a Pd(0) catalyst in improved procedures for the cyanation of aromatic halides, instead of the classical Rosenmund-Von Braun (CuCN) method: Synth. Commun., 24, 557 (1994); Tetrahedron Lett., 40, 8193 (1999); 41, 3271 (2000); 45, 1441 (2004). For cyanation of aryl triflates, see: Tetrahedron Lett., 39, 2907 (1998); Synlett, 1207 (1998). For a review of palladium- and copper-catalyzed cyanations, see: Eur. J. Inorg. Chem., 3513 (2003).

Applications

Other References

GHS Hazard and Precautionary Statements

European Union Hazard Statements : H300-EUH032-H310-H330-H400-H410

Fatal if swallowed. Contact with acids liberates very toxic gas. Fatal in contact with skin. Fatal if inhaled. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

European Union Precautionary Statements : P301+P310-P304+P340-P320-P330-P361-P405-P501A

IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Specific treatment is urgent (see label). Rinse mouth. Remove/Take off immediately all contaminated clothing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Risk & Safety

Risk Phrases:	26/27/28-32-50/53
Very toxic by inhalation, in contact with skin and if swallowed. Contact with acids liberates very toxic gas. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Phrases:	7-28-29-45-60-61
Keep container tightly closed. Do not empty into drains. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and/or its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/Safety data sheets
TSCA:	Yes
RTECS:	ZH1575000